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Department Chemie
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Arbeitskreis Prof. Dr. Matthias Bauer
Metallorganische Komplexchemie für nachhaltige Prozesse und Synchrotronstrahlung


X-ray absorption spectroycopy - the Method and Its Applications on CSD in: T. Schneller et al. (Ed.): Chemical solution deposition of functional thin film oxides, Part II
I. Schlipf, M. Bauer, H. Bertagnolli
2013, Springer-Verlag (Wien), 181-212.

X-ray absorption spectroscopy - the Method and its Application in: R.Schäfer, P.C. Schmidt (Ed.): Methods in Physical Chemistry
M. Bauer and H. Bertagnolli
2012, Wiley-VCH (Weinheim)



N-heterocyclic carbene complexes of iron as photosensitizers for light-induced water reduction

P. Zimmer, P. Müller, L. Burkhardt, R. Schepper, A. Neuba, J. Steube, F. Dietrich, U. Flörke, S. Mangold, M. Gerhards, M. Bauer*

Eur. J. Inorg. Chem., accepted, DOI: 10.1002/ejic.201700064.

Eur. J. Inorg. Chem., accepted, DOI: 10.1002/ejic.201700064. Structual Transitions and Thermochromism of Cobalt(II)-4-Octadecyl-1,2,4-triazole Polymers
I. Bräunlich, C. Mair, M. Bauer, P.Smith, W.Caseri*

J. Inorg. Organomet. Polym. Mat., accepted.

Experimental and Theoretical High-Energy-Resolution X-ray Absorption Spectroscopy: Implications for the Investigation of the Entatic State

N. J. Vollmers, P. Müller, A. Hoffmann,  S. Herres-Pawlis, M. Rohrmüller, W. G. Schmidt, U. Gerstmann*, M. Bauer*

Inorg. Chem.2016, 55, 11694-11706.

Pollution Control Meets Sustainability: Structure-Activity Studies on New Iron Oxide-Based CO Oxidation Catalysts

R. Schoch, M. Bauer
ChemSusChem2016, 9, 1996-2004.


Efficient biomimetic hydrolation catalysis with a bis(pyrazolyl)imidazolylmethane copper-peroxide complex

C. Wilfer, P. Liebhäuser, A. Hoffmann, H. Erdmann, O. Grossmann, R. Schepper, R. Dick, M. Bauer, M. Dürr, I. Ivanovíc-Burmazovic, S. Herres-Pawlis*
Chem. Europ. J., 2015, 2117639-17649.

Mit Röntgenabsorption chemische Prozesse verstehen
M. Bauer
Nachrichten aus der ChemieJuli/August 201563, 771-776.

Experimentelle und theoretische Untersuchung der Existenz von CuII, CuIII, und CuIV in Kupfercorrolen
W. Sinha, M. G. Sommer, N. Deibel, F. Ehret, M. Bauer, B. Sarkar, S. Kar
Angew. Chem., 2015, 127, 13973-13978.

Experimental and Theoretical investigations of the Existence of CuII, CuIII, and CuIV in Copper Corrolato Complexes
W. Sinha, M. G. Sommer, N. Deibel, F. Ehret, M. Bauer, B. Sarkar, S. Kar
Angew. Chem. int. Ed.201554, 13769-13774.

Cobalt-based nanocatalyst for green oxidation and hydrogenation processes
R. V. Jagadeesh, T. Stemmler, A.-E. Surkus, M. Bauer, K. Junge, H. Junge, M. Beller*
Nature Protocols, 2015, 10, 916-926.

Hydrolytic stability and peroxide activation by zirconium-based oxoclusters: a comparative study
F. Faccioli, M. Bauer, D. Pedron, A. Sorarù, M. Carraro, S. Gross*
Eur. J. Inorg. Chem., 2015, 210-225.

Synthesis and characterization of bimetallic metal-organic framework Cu-Ru-BTC
M. A. Gotthardt, R. Schoch, S. Wolf, M. Bauer*, W. Kleist*
Dalton Trans., 2015, 44, 2052-2056.

A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles
D. Dehe, L. Wang, M. K. Müller, G. Dörr, Z. Zhou, R. N. Klupp Taylor, Y. Sun, S. Ernst, M. Hartmann, M. Bauer, W. R. Thiel*
Chem. Cat. Chem., 2015, 7, 127-136.

Design of a highly porous single site catalyst via two-step post-synthetic modification of mixed linker MIL-53(Al)
M. A. Gotthardt, R. Schoch, T. S. Brunner, M. Bauer*, W. Kleist*
Chem. Plus. Chem., 2015, 80, 188-195.

Co-catalyst designing: A regenerable molybdenum containing ternary co-catalyst system for efficient photocatalytic water splitting
G. W. Busser, B. Mei, P. Weide, P. C. K. Vesborg, I. Chorkendorff, K. Stührenberg, M. Bauer, X. Huang, M.-G. Willinger, R. Schlögl, M. Muhler*
ACS Catal.2015, 5, 5530-5539.

High-Resolution X-ray Absorption Spectroscopy of Iron Carbonyl Complexes
A. Atkins, C. Jakob*, M. Bauer*
Phys. Chem. Chem. Phys.2015, 17, 13937-13948.


Configuration Determination of Transition Metal Complexes by Multiple Scattering EXAFS Analysis: A Case Study
M. Bauer
Zeitschr. f. Physik. Chemie, 2014, 228, 1077-1088.

Gels, Xerogels and Films of Polynuclear Iron(II)-Aminotriazole Spin crossover Complexes
A. Sánchez-Ferrer, I. Bräunlich, J. Ruokolainen, M.Bauer, R.Schepper, P.Smith, W. Caseri, R. Mezzenga*
RSC Advances, 2014, 4, 60842-60852.

A new iron based CO oxidation catalyst: Structure-activity correlation
R. Schoch, H.Huang, V. Schünemann, M. Bauer*
Chem. Phys. Chem., 2014, 15, 3768-3775.

BOX Ligands in Biomimetic Copper-Mediated Dioxygen Activation – A New Hemocyanin Model
A. Walli, S. Dechert, M. Bauer, S. Demeshko, F. Meyer*
Eur. J. Inorg. Chem., 2014, 4660-4676.

Base-free non-noble metal catalyzed Hydrogen Generation from Formic Acid – Scope and Mechanistic Insights
D. Mellmann, E, Barsch, M. Bauer, K. Grabow, A. Boddien, A. Kammer, P. Sponholz, U. Bentrup, R. Jackstell, H. Junge, G. Laurenczy, R. Ludwig*, M. Beller*
Chem. Eur. J., 2014, 20, 13589-13602.

Catalytic system for the activation of diorganozinc reagents
T. Werner*, M. Bauer*, A.M. Rihai, H. Schramm
Eur. J. Org. Chem., 2014, 22, 4876-4883.

A series of amide functionalized isoreticular metal organic frameworks
E. Keceli, M. Hemgesberg, R. Grünker, V. Bon, C. Wilhelm, T. Philippi, R. Schoch, Y. Sun, M. Bauer, S. Ernst, S. Kaskel, W.R. Thiel*
Micropor. Mesopor. Mater., 2014, 194, 115–125.

HERFD-XAS and valence-to-core XES: New tools to push the limits in research with hard X-rays?
M. Bauer*
Phys. Chem. Chem. Phys., 2014, 16, 13827-13837.

Der elektronische Grundzustand von [Fe(CO)3(NO)]: Eine spektroskopische und theoretische Studie
J. E. M. N. Klein, B. Miehlich, M. S. Holzwarth, M. Bauer, M. Milek, M. M. Khusniyarov, G. Knizia, H.-J. Werner, B. Plietker*
Angew. Chem., 2014, 126, 1820–1824.
Angew. Chem. Int. Ed., 2014, 53, 1790-1794.

Spin-crossover iron(II)-aminotriazole coordination polymers in solution
I. Bräunlich, A. Sánchez-Ferrer, M. Bauer, R. Schepper, P. Knüsel, J. Dshemuchadse, R. Mezzenga, P. Smith, W. Caseri*
Inorg. Chem., 2014, 53, 3546 - 3557.

On the Selective Aerobic Oxidation of Benzyl Alcohol with Pd/Au-Nanoparticles in Batch and Flow
H. Alex, N. Steinfeldt, K. Jähnisch, M. Bauer*, S. Hübner*
Nanotechnol. Rev.20143, 99-110.


Valence-to-Core X-ray Emission Spectroscopy of Iron Carbonyl Complexes: Implications for the Examination of Catalytic Intermediates
M.U. Delgado-Jaime, S. DeBeer*, M. Bauer*
Chem. Eur. J., 2013, 19, 15888-15897.

The active species in iron-catalyzed cross-coupling reactions by X-ray absoprtion spectroscopy
R. Schoch, W. Desens, Th. Werner*, M. Bauer*
Chem. Eur. J., 2013, 19, 15816 - 15821.

Trinuclear diamagnetic nickel(II) complexes bridged by 3-arylpyrazolato ligands
K.S.M. Salih, S. Bergner, H. Kelm, Y. Sun, A. Grün, Y. Schmitt, R. Schoch, M. Busch, N. Deibel, S. Bräse, B. Sarkar, M. Bauer, M. Gerhards, W.R. Thiel*
Eur. J. Inorg. Chem., 2013, 6049 - 6059.

Direct observation of charge transfer in solvated organometallic complex
E. Suljoti, R. Garcia-Diez, S. Bokarev, K. M. Lange, R. Schoch, B. Dierker, M. Dantz, K. Yamamoto, N. Engel, K. Atak, O. Kühn, J.-E. Rubensson, M. Bauer*, E. F. Aziz*
Angew. Chem., 2013, 125, 10024–10027.
Angew. Chem. Int. Ed., 2013, 52, 9841-9844.

The chemical sensitivity of X-ray spectroscopy: High energy resolution XANES versus valence-to-core X-ray emission spectroscopy of substituted ferrocenes
A. Atkins, C. Jacob, M. Bauer
Phys. Chem. Chem. Phys., 2013, 15, 8095-8105.

Maximum hydrogen chemisorption on KL zeolite supported Pt cluster
Chr. Jensen, D. Buck, H. Dilger, M. Bauer, F. Phillipp, E. Roduner*
Chem. Commun., 2013, 49, 588-590.

Formation, operation and deactivation of Cr catalysts in ethylene tetramerization directly assessed by operando EPR and XAS
J. Rabeah, M. Bauer, W. Baumann, A.E.C. McConnell, W.F. Gabrielli, P.B. Webb, D. Selent, A. Brückner*
ACS Catalysis, 2013, 3, 95-102.

Hierarchically structured copper gallium spinels through microwave hydrothermal methods
F. Conrad, M. Bauer, S. Weyeneth, Y. Zhou, K. Hametner, D. Günther, G.R. Patzke*
Solid State Sci., 2013, 24, 125-132.


Synthesis and Characterization of Vanadium-Doped LiMnPO4 - Compounds - LiMn(PO4)x(VO4)1-x (0.8 ≤ x ≤ 1.0)
O. Clemens*, M. Bauer, R. Haberkorn, M. Springborg, H.P. Beck
Chem. Mater., 2012, 24, 4717-4724.

The role of Pd2+/Pd0 in hydrogenation by [Pd(2-pymo)2]n: A combined X-ray absorption and IR spectroscopic study
S. Schuster, E. Klemm*, M. Bauer*
Chem. Eur. J., 2012, 18, 5831-15837.

Structure-activity studies on highly active palladium hydrogenation catalysts by X-ray absorption spectroscopy
M. Bauer*, R. Schoch, L. Shao, B. Zhang, A. Knop-Gericke, M.-G. Willinger, R. Schlögl, D. Teschner*
J. Phys. Chem. C., 2012, 116, 22375-22385.

Generation and characterisation of the phenoxyl-radical containing CuII complex [Cu(triaz)2]+ (triaz = O, N chelating triazole-phenolate)
K. Butsch, A. Klein*, S. Nitsche, K. Stirnat, J.R. Hawkett, E. J. L. McInnes, M. Bauer
Dalton Trans., 2012, 41, 11464-11475.

Water Oxidation with molecular-defined Iridium complexes: Insights into Homogeneous vs. Heterogeneous Catalysis
H. Junge, N. Marquet, A. Kammer, S. Denurra, M. Bauer*, S. Wohlrab, F. Gärtner, M.-M. Pohl, A. Spannenberg, S. Gladiali, M. Beller*
Chem. Eur. J., 2012, 18, 12749-12758.

Probing the electronic structure of substituted ferrocenes with high resolution XANES spectroscopy
A. J. Atkins, C.R. Jacob*, M. Bauer*
Chem. Eur. J., 2012, 18, 7021-7025.

New Spinel-type catalysts for visible-light-driven water oxidation
F. Conrad, M. Bauer, D. Sheptyakov, S. Weyeneth, D. Jaeger, K. Hametner, P.-E. Car, J. Patscheider, D. Günther, G.R. Patzke*
RSC Advances, 2012, 2, 3076-3082.

Iron(0) Particles: Catalytic Hydrogenations and Spectroscopic Studies
A. Welther, M. Bauer*, M. Mayer, A. Jacobi von Wangelin*
Chem. Cat. Chem., 2012, 4(8), 1088-1093.

Benign Catalysis with Iron: Unique Selectivity in Catalytic Isomerization Reactions of Olefins
R. Jennerjahn, R. Jackstell, I. Piras, R. Franke, H. Jiao, M. Bauer, and M. Beller*
Chem. Sus. Chem., 2012, 5 (4), 734-739.

Paramagnetic Palladacycles with PdIII Centers are Highly Active Catalysts for Asymmetric Aza-Claisen Rearrangements
S.H. Eitel, M. Bauer*, D. Schweinfurth, B. Sarkar*, H. Kelm, H.-J. Krüger*, W. Frey, R. Peters*
J. Am. Chem. Soc., 2012, 134 (10), 4683–4693.


Highly flexible O,O',N ligands and their Fe, Ni, Cu and Zn complexes
K. Butsch, A. Klein*, M. Bauer
Inorg. Chim. Acta., 2011, 374, 350-358.

On the Existence of LiFeVO4– Tales and Imagination
O. Clemens, M. Bauer, R. Haberkorn, H.P. Beck*
Z. Anorg. Allg. Chem., 2011, 637, 1036-1044.

Insights into the ultrafast electron delocalization for iron carbonyls using dark channel fluorescence yield X-ray absorption
M. Bauer*, T. Stalinski, E.F. Aziz*
Chem. Phys. Chem., 2011, 12, 2088-2091.

Catching the state of Pt in SnO2-based sensors under working conditions
M. Hübner, D. Koziej, M. Bauer, N. Barsan, K. Kvashnina, M.D. Rossell, U. Weimar, J.-D. Grunwaldt*
Angew. Chem. Int. Ed., 2011, 50, 2841-2844.
Struktur und Verhalten von Platin in SnO2-basierten Gassensoren unter realistischen Arbeitsbedingungen
Angew. Chem., 2011, 123, 2893-2896.

From thioxocluster to dithiocluster: exploring the chemistry of polynuclear Zr complexes with S,O and S,S ligands
F. Maratini, L. Pandolfo, M. Bendova, U. Schubert, M. Bauer, M. Rocchia, A. Venzo, E. Tondello, S. Gross*
Inorg. Chem., 2011, 50, 489.


The chemical information contained in the EXAFS Debye-Waller factor: Covalency in Iron(III) bis-diketonato complexes
M. Bauer*
J. Phys. Chem. A, 2010, 114, 12870-12874.

Adsorption of Oxygen on Copper in Cu/HZSM5 Zeolites
A. B. Ene, M. Bauer, T. Archipov, E. Roduner*
Phys. Chem. Chem. Phys., 2010, 12, 6520-6531.

EXAFS as powerful analytical tool for the investigation of organic-inorganic hybrid materials (invited feature article)
S. Gross*, M. Bauer*
Adv. Funct. Mat., 2010, 20, 4026.

X-ray absorption in homogeneous catalysis reasearch: The iron-catalyzed Michael addition reaction by XAS, RIXS and multi-dimensional spectroscopy
M. Bauer*, Chr. Gastl
Phys. Chem. Chem. Phys., 2010, 12, 5575-5584.

Two-dimensional spectroscopic set-up for simultaneous UV-Vis/(Q)EXAFS in-operando studies of homogeneous reactions under laboratory conditions
M. Bauer*, G. Heusel, S. Mangold, H. Bertagnolli
J. Synchr. Rad., 2010, 17, 273-279.

A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium (IV) dicarboxylates
V. Guillerm, S. Gross, C. Serre, T. Devic, M. Bauer, G. Férey
Chem. Commun., 2010, 46, 767.


Syntheses, Crystal structures, Spectroscopic Properties and Catalytic Aerobic Oxidations of Novel Trinuclear Non-heme Iron Complexes
V. Rabe, W. Frey, A. Baro, S. Laschat*, M. Bauer, H. Bertagnolli, S. Rajagopalan, T. Asthalter, E. Roduner, H. Dilger, T. Glaser, D. Schnieders
Eur. J. Inorg. Chem., 2009, 4660.

First example of functional chromium wheel-based hybrid organic-inorganic materials for dielectric applications
V. Di Noto, A. Boeer, S. Lavina, C.A. Muryn, M. Bauer, G.A. Timco, G. Pace, M. Rancan, R.E.P. Winpenny, S. Gross*
Adv. Func. Mat., 2009, 19, 3226-3236.

Alkoxide clusters in solution: An EXAFS study of the example Y(OEtOMe)3 and the degradation induced by structural modifiers
M. Bauer*, H. Bertagnolli
Z. Phys. Chem., 2009, 223, 877.

Towards X-ray absorption spectroscopy in real time
M. Bauer*, H. Bertagnolli
Chem. Phys. Chem., 2009, 10, 2197-2200.


UV-photopolymerisation of poly(methyl methacrylate)-based inorganic–organic hybrid coatings and bulk samples reinforced with methacrylate-modified zirconium oxocluster
F. Graziola, F. Girardi, M. Bauer, R. Di Maggio, M. Rovezzi, H. Bertagnolli, C. Sada, G. Rossetto, S. Gross*
Polymer, 2008, 49, 4332-4343.

Microemulsion Approach to Neodymium, Europium, and Ytterbium Oxide/Hydroxide Colloids - Effects of Precursors and Preparation Parameters on Particle Size and Crystallinity
Chr. Rill, M. Bauer, H. Bertagnolli, G. Kickelbick*
Journal of Colloid and Interface Science, 2008, 325, 179-186.

Platinum species in the pores of NaX, NaY and NaA zeolites studied using EPR, XAS and FTIR spectroscopies
Y. Akdogan, C. Vogt, M. Bauer, H. Bertagnolli, L. Giurgiu, E. Roduner*
Phys. Chem. Chem. Phys., 2008, 10, 2952-2963.

Ordered Mesoporous Thin Films of Rutile TiO2 Nanocrystals Mixed with Amorphous Ta2O5
J.-M. Wu, M. Antonietti, S. Gross, M. Bauer, B. M. Smarsly*
Chem. Phys. Chem., 2008, 9, 748-757.


X-ray absorption spectroscopy - The Method and its application
M. Bauer*, H. Bertagnolli
Bunsen-Magazin, 9. Jahrgang, 6/2007, 216-231.

The Amplitude Reduction Factor and the Cumulant Expansion Method: Crucial Factors in the Structural Analysis of Alkoxide Precursors in Solution
M. Bauer*, H. Bertagnolli
J. Phys. Chem. B 2007, 111, 13756-13764.

The structures of the precursor Hf(OnBu)4 and its modification in solution: EXAFS-investigation in combination with XANES- and IR-spectroscopy
M. Bauer*, S. Müller, G. Kickelbick, H. Bertagnolli
New J. Chem. 2007, 31, 1950-1959.

Structure and Magnetization of Small Monodisperse Platinum Clusters
X. Liu, M. Bauer, J. van Slageren, F. Phillipp, H. Bertagnolli, E. Roduner*
Virtual Journal of Nanoscale Science and Technol. 2007, 15(1).


Structure and Magnetization of Small Monodisperse Platinum Clusters
X. Liu, M. Bauer, J. van Slageren, F. Phillipp, H. Bertagnolli, E. Roduner*
Phys. Rev. Lett. 2006, 97, 2534011-4.

Synthesis and characterization of orthorhombic, 2d-centered rectangular and lamellar iron oxide doped silica films
R. Supplit, N. Hüsing*, H. Bertagnolli, M. Bauer, V. Kessler, G.A. Seisenbaeva, S. Bernstorff, S. Gross
J. Mater. Chem. 2006, 16, 4443-4453.

EXAFS Spectroscopy of the Alkoxide Precursor Zr(OnBu)4 and its Modification in Solution
M. Bauer*, Chr. Gastl, Chr. Köppl, G. Kickelbick, H. Bertagnolli
Monatsh. Chem. - Chemical Monthly 2006, 137, 567–581.

Investigations into the metal species of the homogeneous iron(III) catalyzed Michael addition reaction
M. Bauer*, Th. Kauf, J. Christoffers, H. Bertagnolli
Phys. Chem. Chem. Phys. 2005, 7(13), 2664-2670.

Influence of additives and post-synthesis treatment on the structural properties of sol-gel prepared alumina-doped zirconia studied by EXAFS-spectroscopy and X-ray diffraction
M.P. Feth*, M. Bauer, G. Kickelbick, O. Metelkina, U. Schubert, H. Bertagnolli
J. Non-cryst. Sol. 2005, 351, 432-443.


Confined phonons in glasses - A study by nuclear inelastic absorption and Raman scattering
T. Asthalter*, M. Bauer, U. van Bürck, A.I. Chumakov, I. Sergueev, H. Franz
Eur. Phys.J. 2003 E 12, S1, 9.

Structural Investigation of High-Valent Salen Manganese Complexes by UV/Vis-, Raman, XANES- and EXAFS-Spectroscopy
M.P. Feth, C. Bolm, J.P. Hildebrand, M. Köhler, O. Beckmann, M. Bauer, R. Ramamonjisoa, H. Bertagnolli*
Chem. Eur. J. 2003, 9, No.6, 1348-1359.

Phonons in confinement and the Boson Peak using nuclear inelastic absorption
T. Asthalter*, M. Bauer, U. van Bürck, I. Sergueev, H. Franz, A.I. Chumakov
Hyperfine Int. 2002, 144/145, 77.


Prof. Dr. Matthias Bauer

Anorganische Chemie - Arbeitskreis Bauer

Metallorganische Komplexchemie für nachhaltige Prozesse und Synchrotronstrahlung

Matthias Bauer
+49 5251 60-5614

Die Universität der Informationsgesellschaft