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Department Chemie
Organische Chemie
Prof. Dr. René Wilhelm
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Reactivity of Grubbs-Hoveyda II Complexes including Extended N-Heterocyclic Carbenes with a Bicyclic Camphor-Based Framework. Rais, E.; Flörke, U.; Wilhelm, R. Synthesis 2017, 49, 2852-2864.

A Sophisticated Approach towards a New Class of Copper(I)-Sulfur Cluster Complexes with Imidazolinium-Dithiocarboxylate Ligands. Ortmeyer, J.; Flörke, U.; Henkel, G.; Wilhelm, R.; Neuba, A. Eur. J. Inorg. Chem. 2017, 3191-3197.

The Use of Stable Carbene-CO2 Adducts for the Polymerization of Trimethylene Carbonate. Reitz, A. K.; Sun, Q.; Wilhelm, R.; Kuckling, D. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 820-829.

Synthesis and Investigation of New Cyclic Haloamidinium Salts. Rais, E.; Flörke, U.; Wilhelm, R. Z. Naturforsch. 2016, 71b, 667-676. 

Straightforward Diastereoselective Synthesis of P-chirogenic (1R)-1,8,8-Trimethyl-2,4-diaza-3-phosphabicyclo[3.2.1]octane 3-Oxides. Application as Chiral NMR Solvating Agents. Uzarewicz-Baig, M.; Wilhelm, R. Heteroatom Chem. 2016, 27, 121-134. 

Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction. Muntzeck, M.; Wilhelm, R. Int. J. Mol. Sci. 2016, 17, 860-868. 

Chiral Imidazolinium Salts with TIPS Groups for the Palladium Catalyzed alpha-Arylation and as Chiral Solvating Agents. Gilani, M. A.; Rais, E.; Wilhelm, R. Synlett 2015, 26, 1638-1641. 

Crystal Structure of Tris(1,3-dimesityl-4,5-dihydro-1H-imidazol-3-ium) tetrabromidocobaltate(II) bromide chloroform hexasolvate. Rais, E.; Flörke, U.; Wilhelm, R. Acta Cryst. 2015, E71, m177-m178. 

Crystal Structure of Dibromidobis(1,3-dibenzyl-1,3-diazinan-2-one-κO)cobalt(II). Rais, E.; Flörke, U.; Wilhelm, R. Acta Cryst. 2015, E71, m160-m161. 

Crystal structures of diiodidobis[(1S,5S )-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3]palladium(IV) and dichlorido[(1S,5S )-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3](triphenylphosphane-κP )palladium(IV). Rais, E.; Flörke, U.; Wilhelm, R. Acta Cryst. 2015, E71, 919-922.

Synthesis of New Camphor-Based Carbene Ligands and Their Application in a Copper Catalyzed Michael Addition with B2Pin2. Koppenwallner, M.; Rais, E.; Uzarewicz-Baig, M.; Tabassum, S.; Gilani, M. A.; Wilhelm, R. Synthesis 2015, 47, 789-800. 

Synthesis of New Copper(I) Based Linear 1-D-Coordination Polymers with Neutral Imidazolinium-Dithiocarboxylate Ligands. Neuba, A.; Ortmeyer, J.; Konieczna, D. D.; Weigel, G.; Flörke, U.; Henkel, G.; Wilhelm, R. RSC Adv. 2015, 5, 9217-9220. 

Highly Regioselective Synthesis of Chiral Diamines via a Buchwald-Hartwig Amination from Camphoric Acid and their Application in the Henry Reaction. Uzarewicz-Baig, M.; Koppenwallner, M.; Tabassum, S.; Wilhelm, R. Appl. Organometal. Chem. 2014, 28, 552-559. 

Investigation of Imidazol(in)ium-dithiocarboxylates as Sensors for the Detection of Mercury(II) and Silver(I) Ions. Konieczna, D. D.; Blanrue, A.; Wilhelm, R. Z. Naturforsch. 2014, 69b, 596-604.

Ring Opening Polymerization of Organic Carbonates Using CO2-Carbene Adducts as Effective Organocatalyst. Reitz, A.; Wilhelm, R.; Kuckling D. Macromol. Symp. 2013, 334, 92-97. 

Chiral Ionic Liquids Based on Nicotine for the Chiral Recognition of Carboxylic Acids. Heckel, T.; Winkel, A.; Wilhelm, R. Tetrahedron: Asymmetry 2013, 24, 1127-1133. 

An Ionic Liquid Solution of Chitosan as Organocatalyst. Heckel, T.; Konieczna, D. D.; Wilhelm, R. Catalysts 2013, 3, 914-921. 

Invited book chapter: Non-covalent Activation - Lewis Acids. Heckel, T.; Wilhelm, R. in Comprehensive Enantioselective Organocatalysis, ed. Dalko, P. I.; Wiley-VCH, Weinheim, 2013, p.413.  

Imidazolinium and Amidinium Salts as Lewis Acid Organocatalysts. Sereda, O.; Clemens, N.; Heckel, T.; Wilhelm, R. Beilstein J. Org. Chem. 2012, 8, 1798-1803. 

Imidazolinium Sulfonate and Sulfamate Zwitterions as Chiral Solvating Agents for Enantiomeric Excess Calculation. Tabassum, S.; Gilani; M.; Wilhelm, R. Tetrahedron: Asymmetry 2011, 22, 1632-1639. 

New Chiral Ionic Liquids Based on Enantiopure Sulphate and Sulfonate Anions for Chiral Recognition. Winkel, A.; Wilhelm, R. Eur. J. Org. Chem. 2010, 5817-5824.

Invited Review: Lewis Acid Organocatalysts. Sereda, O.; Tabassum, S.; Wilhelm, R. Top. Curr. Chem. 2010, 291, 349-393 . 

New Chiral Ionic Liquids Based on Imidazolinium Salts. Winkel, A.; Wilhelm, R. Tetrahedron: Asymmetry 2009, 20, 2344-2350. 

New Enantiopure NHCs Derived from Camphor. Reddy, P. V. G.; Tabassum, S.; Blanrue, A.; Wilhelm, R. Chem. Commun. 2009, 5910-5912. 

Hindered Brønsted Bases as Lewis Base Catalysts. Tabassum, S.; Sereda, O.; Reddy, P. V. G.;Wilhelm, R. Org. Biomol. Chem. 2009, 7, 4009-4016. 

Enantiopure Imidazolinium Dithiocarboxylates as Highly Selective Novel Organocatalysts. Sereda, O.; Blanrue, A.; Wilhelm, R. Chem. Commun. 2009, 1040-1042. 

Methylated Imidazolinium-Dithiocarboxylates: Two Representatives of a New Class of Ionic Liquids. Blanrue, A.; Wilhelm, R. Synthesis 2009, 583-586. 

New Enantiopure Imidazolinium Carbene Ligands Incorporating Two Hydroxy Groups for Lewis Acid Catalyzed Diethyl Zinc Addition to Aldehydes. Gilani, M.; Wilhelm, R. Tetrahedron: Asymmetry 2008, 19, 2346-2352. 

Influence of the Substitution Pattern of Cp-Iron-Arene Salts in the Solid-State Synthesis of New Carbon Nanostructures. Winkel, A.; Jain, D.; Wilhelm, R. Organometallics 2008, 27, 3430-3434. 

Invited Review: Recent Advances in the Synthesis and Application of Chiral Ionic Liquids. Winkel, A.; Reddy, P. V. G.; Wilhelm, R. Synthesis 2008, 999-1016. 

Hexamethyldisilazane Sodium Salt as Highly Active Lewis Base Catalyst for the Staudinger Reaction. Sereda, O.; Wilhelm, R. Synlett 2007, 3032-3036. 

Invited Paper: Solid-State Synthesis of Carbon-Nanostructures. Wilhelm, R.; Winkel, A.; Jain, D. J. Fudan University (Natural Science) 2007, 46, 701-702. 

An Easy Way to Produce a-Iron Filled Multiwalled Carbon Nanotubes. Jain, D.; Wilhelm, R. Carbon 2007, 45, 602-606. 

Easy Accessible Chiral Bis-Hydroxy Imidazolinium Salts as Shift Reagents and Carbene Precursors. Jurčík, V.; Gilani, M.; Wilhelm, R. Eur. J. Org. Chem. 2006, 5103-5109. 

Preparation of New Enantiopure Imidazolinium Salts and Their Evaluation as Catalysts and Shift Reagents. Jurčík, V.; Wilhelm, R. Tetrahedron: Asymmetry 2006, 17, 801-810. 

Unexpected Behaviour of Tosylated and Acetylated Imidazolinium Salts. Clemens, N.; Sereda, O.; Wilhelm, R. Org. Biomol. Chem. 2006, 4, 2285-2290. 

Solid-State Synthesis of Well Defined Carbon Nanocapsules from Organometallic Precursors. Jain, D.; Winkel, A.; Wilhelm, R. Small 2006, 2, 752-755. 

Synthesis of Enantiopure Tricarbonyl(indan-1,2-dione)chromium. Leinweber, D.; Weidner, I.; Wilhelm, R.; Wartchow, R.; Butenschön, H. Eur. J. Org. Chem. 2005, 5224-5235. 

An Imidazolinium Salt as Ionic Liquid for Medium and Strong Bases. Jurčík, V.; Wilhelm, R. Green Chem. 2005, 7, 844-848. 

Imidazolinium Salts as Catalysts for the aza-Diels-Alder Reaction. Jurčík, V.; Wilhelm, R. Org. Biomol. Chem. 2005, 3, 239-244. 

Imidazolinium-Carbodithioate Zwitterions as Organocatalysts for the Cyanosilylation of Aldehydes. Blanrue, A.; Wilhelm, R. Synlett 2004, 2621-2623. 

Preparation of Aminals in Water. Jurčík, V.; Wilhelm, R. Tetrahedron 2004, 60, 3205-3210. 

Near-Quantitative Solid-State Synthesis of Carbon Nanotubes from Homogeneous Diphenylethynecobalt and -Nickel Complexes. Iyer, V. S.; Vollhardt, K. P. C.; Wilhelm, R. Angew. Chem. 2003, 115, 4515-4519; Angew. Chem. Int. Ed. 2003, 42, 4379-4383. 

Palladium Catalysed Suzuki Reactions of Fluoroarenes. Widdowson, D. A.; Wilhelm, R. Chem. Commun. 2003, 578-579. 

A Computational Study of the Mechanism of Palladium Insertion into Alkynyl and Aryl Carbon–Fluorine Bonds. Jakt, M.; Johannissen L.; Rzepa, H. S.; Widdowson, D. A.; Wilhelm, R. J. Chem. Soc., Perkin Trans. 2 2002, 576-581. 

The Tricarbonylchromium Complex of a Trimethyltin-Substitued N‑(Triisopropylsilyl)indole - A Dynamic NMR Study of Multiple Independent Rotation Processes in the Solid State with an X-ray Diffraction Structure and Molecular Mechanics Calculations. Aliev, A. E.; Anderson, J. E.; Butler, D.; Gonzalez-Quteirino, J.; Lunazzi, L.; Mazzanti, A.; Steed, J. W.; Wilhelm, R. Eur. J. Inorg. Chem. 2002, 133-140. 

Dilithiation of Arenetricarbonylchromium(0) Complexes with Enantio-selective Quench: Application to Chiral Biaryl Synthesis. Tan, Y.-L.; White, A. J. P.; Widdowson, D. A.; Wilhelm, R.; Williams, D. J. J. Chem. Soc., Perkin Trans. 1 2001, 3269-3280. 

Reversal of Asymmetric Induction in Arenetricarbonylchromium(0) Complexes via Dilithiation with the (–)-Sparteine / BuLi System and Enantioselective Quench. Tan, Y.-L.; Widdowson, D. A.; Wilhelm, R. Synlett 2001, 1632-1634. 

Asymmetric Synthesis of a Fully Protected ent-Actinoidinic Acid. Wilhelm, R.; Widdowson, D. A. Org. Lett. 2001, 3, 3079–3082. 

Asymmetric Deprotonation – Substitution of Arenetricarbonylchromium(0) Complexes: Substituent Controlled Lithiation with the Butyllithium-Sparteine System. Wilhelm, R.; Sebhat, I. K.; White, A. J. P.; Williams, D. J.; Widdowson, D. A. Tetrahedron: Asymmetry 2000, 11, 5003-5016. 

Palladium Catalyzed Cross-coupling of (Fluoroarene)tricarbonylchromium(0) Complexes. Wilhelm, R.; Widdowson, D. A. J. Chem. Soc., Perkin Trans. 1 2000, 3808-3813. 

Directed Lithiation in Arenetricarbonylchromium(0) Complexes: Assessment of Some Directing Group Specificities and of Electrophilic Quench Efficacies. Sebhat, I. K.; Tan, Y.-L.; Widdowson, D. A.; Wilhelm, R.; White, A. J. P.; Williams, D. J. Tetrahedron 2000, 56, 6121-6134. 

Palladium Catalyzed Cross-coupling of (Fluoroarene)tricarbonylchromium(0) Complexes.  Widdowson, D. A.; Wilhelm, R. Chem. Commun. 1999, 2211-2212.


Prof. Dr. René Wilhelm

Organische Chemie - Arbeitskreis Wilhelm

Professor für Organische Chemie

René Wilhelm
+49 5251 60-5766
+49 5251 60-3245

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